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Membrane Technology and Applications cover

Membrane Technology and Applications

by Richard W. Baker

4th Edition

Publisher: John Wiley & Sons P&T

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Chemical Engineering

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Book Details

Print ISBN9781119685982
eText ISBN9781119685999
PublisherJohn Wiley & Sons P&T
Publishing Year2023
Edition4th Edition
LanguageEnglish
Pages560

Membrane Technology and Applications, 4th Edition presents systematic coverage of separation membrane theory, manufacture, and engineering applications. Authored by Richard W. Baker, this textbook introduces core operational concepts for synthetic membrane separation processes. The opening sections establish essential physical foundations required to analyze fluid transport, membrane structures, module configurations, and operational parameters.

General introductory chapters examine membrane preparation techniques, transport theory, and concentration polarization effects. The text then investigates individual process types, including electrodialysis, pervaporation, microfiltration, and coupled and facilitated transport mechanisms. Further sections address medical applications of membranes, detailing technical principles behind specialized healthcare separations and therapeutic devices.

A defining structural addition to this 4th Edition is a new chapter on transport mechanisms in finely microporous membranes, focusing directly on gas transport principles. The textbook provides structured educational support for graduate students, academic researchers, and industry professionals seeking rigorous separation engineering knowledge.

Table of Contents

  1. Chapter 1: Overview of Membrane Science and Technology

    • • 1.1 Introduction
    • • 1.2 Historical Development of Membranes
    • • 1.3 Membrane Transport Theory
    • • 1.4 Types of Membranes
    • • 1.4.1 Isotropic Membranes
    • • 1.4.2 Anisotropic Membranes
    • • 1.4.3 Membranes with Special Features
    • • 1.5 Membrane Processes
    • • 1.5.1 Reverse Osmosis, Ultrafiltration, Microfiltration
    • • 1.5.2 Electrodialysis
    • • 1.5.3 Gas Separation
    • • 1.5.4 Pervaporation
    • • 1.5.5 Hyperfiltration
    • • 1.5.6 Membrane Contactors
    • • 1.5.7 Carrier Transport
    • • 1.5.8 Medical Applications
    • • References
  2. Chapter 2: Membrane Transport Theory – Solution-Diffusion

    • • 2.1 Introduction
    • • 2.2 The Solution-Diffusion Model
    • • 2.2.1 Molecular Dynamics Simulations
    • • 2.2.2 Concentration and Pressure Gradients in Membranes
    • • 2.2.3 Application of the Solution-Diffusion Model to Specific Processes
    • • 2.2.4 A Unified View
    • • 2.3 Structure–Permeability Relationships in Solution-Diffusion Membranes
    • • 2.3.1 Diffusion Coefficients
    • • 2.3.2 Sorption Coefficients in Polymers
    • • 2.4 Conclusions
    • • References
  3. Chapter 3: Microporous Membranes – Characteristics and Transport Mechanisms

    • • 3.1 Introduction
    • • 3.2 Gas Separation in Microporous Membranes
    • • 3.2.1 Membrane Categories
    • • 3.2.2 Crystalline Finely Microporous Membranes
    • • 3.2.3 Amorphous Microporous Membranes
    • • 3.3 Gas Separation: Transport Mechanisms
    • • 3.3.1 Surface Adsorption and Diffusion
    • • 3.3.2 Knudsen Diffusion
    • • 3.3.3 Molecular Sieving
    • • 3.3.4 Pore Blocking
    • • 3.3.5 Summary
    • • 3.4 Liquid Permeation in Microporous Membranes
    • • 3.4.1 Screen Filters
    • • 3.4.2 Depth Filters
    • • 3.5 Conclusions and Future Directions
    • • References
  4. Chapter 4: Membranes and Modules

    • • 4.1 Introduction
    • • 4.2 Isotropic Membranes
    • • 4.2.1 Isotropic Nonporous Membranes
    • • 4.2.2 Isotropic Microporous Membranes
    • • 4.3 Anisotropic Membranes
    • • 4.3.1 Phase Separation Membranes
    • • 4.3.2 Interfacial Polymerization Membranes
    • • 4.3.3 Solution-Coated Composite Membranes
    • • 4.3.4 Repairing Membrane Defects
    • • 4.4 Ceramic and Glass Membranes
    • • 4.4.1 Ceramic Membranes
    • • 4.4.2 Microporous Glass Membranes
    • • 4.5 Other Membranes
    • • 4.6 Hollow Fiber Membranes
    • • 4.7 Membrane Modules
    • • 4.7.1 Plate-and-Frame Modules
    • • 4.7.2 Tubular Modules
    • • 4.7.3 Spiral-Wound Modules
    • • 4.7.4 Hollow Fiber Modules
    • • 4.7.5 Other Module Types
    • • 4.8 Module Selection
    • • 4.9 Conclusions and Future Directions
    • • References
  5. Chapter 5: Concentration Polarization

    • • 5.1 Introduction
    • • 5.2 Boundary Layer Film Model
    • • 5.2.1 Determination of the Peclet Number
    • • 5.3 Concentration Polarization in Liquid Separation Processes
    • • 5.4 Concentration Polarization in Gas Separation Processes
    • • 5.5 Concentration Polarization in Membrane Contactors and Related Processes
    • • 5.6 Conclusions and Future Directions
    • • References
  6. Chapter 6: Reverse Osmosis (Hyperfiltration)

    • • 6.1 Introduction and History
    • • 6.2 Theoretical Background
    • • 6.3 Membrane Materials
    • • 6.3.1 Cellulosic Membranes
    • • 6.3.2 Noncellulosic Loeb–Sourirajan Membranes
    • • 6.3.3 Interfacial Composite Membranes
    • • 6.4 Membrane Performance
    • • 6.5 Reverse Osmosis Membrane Categories
    • • 6.5.1 Seawater Desalination Membranes
    • • 6.5.2 Brackish Water Desalination Membranes
    • • 6.5.3 Nanofiltration Membranes
    • • 6.5.4 Organic Solvent Separating Membranes
    • • 6.6 Membrane Modules
    • • 6.7 Membrane Fouling and Control
    • • 6.7.1 Silt
    • • 6.7.2 Scale
    • • 6.7.3 Biofouling
    • • 6.7.4 Organic Fouling
    • • 6.7.5 Pretreatment
    • • 6.7.6 Membrane Cleaning
    • • 6.8 Applications
    • • 6.8.1 Seawater Desalination
    • • 6.8.2 Brackish Water Desalination
    • • 6.8.3 Industrial Applications
    • • 6.8.4 Organic Solvent Separations
    • • 6.8.5 Conclusions and Future Directions
    • • References
  7. Chapter 7: Ultrafiltration

    • • 7.1 Introduction and History
    • • 7.2 Characterization of Ultrafiltration Membranes
    • • 7.3 Membrane Fouling
    • • 7.3.1 Constant Pressure and Constant Flux Operation
    • • 7.3.2 Concentration Polarization
    • • 7.3.3 Fouling Control
    • • 7.4 Membranes
    • • 7.5 Tangential-Flow Modules and Process Designs
    • • 7.5.1 Modules
    • • 7.5.2 Process Design
    • • 7.6 Applications
    • • 7.6.1 Industrial Applications
    • • 7.6.2 Municipal Water Treatment/Membrane Bioreactors (MBRs)
    • • 7.6.3 Biotechnology
    • • 7.7 Conclusions and Future Directions
    • • References
  8. Chapter 8: Microfiltration

    • • 8.1 Introduction and History
    • • 8.2 Background
    • • 8.2.1 Types of Membrane
    • • 8.2.2 Membrane Characterization
    • • 8.2.3 Microfiltration Membranes and Modules
    • • 8.2.4 Process Design
    • • 8.3 Applications
    • • 8.3.1 Sterile Filtration of Pharmaceuticals
    • • 8.3.2 Microfiltration in the Electronics Industry
    • • 8.3.3 Sterilization of Wine and Beer
    • • 8.4 Conclusions and Future Directions
    • • References
  9. Chapter 9: Gas Separation

    • • 9.1 Introduction and History
    • • 9.2 Dense Polymeric Membranes
    • • 9.2.1 Theoretical Background
    • • 9.2.2 Structural Features and Considerations
    • • 9.3 Microporous Membranes
    • • 9.4 Membrane Modules
    • • 9.5 Process Design
    • • 9.5.1 Pressure Ratio
    • • 9.5.2 Stage-Cut
    • • 9.5.3 Multistep and Multistage System Designs
    • • 9.5.4 Recycle Designs
    • • 9.6 Applications
    • • 9.6.1 Hydrogen Separation
    • • 9.6.2 Air Separation
    • • 9.6.3 Natural Gas Separations
    • • 9.6.4 Organic Vapor/Gas Separations
    • • 9.6.5 To-Be-Developed Applications
    • • 9.7 Conclusions and Future Directions
    • • References
  10. Chapter 10: Pervaporation/Vapor Permeation

    • • 10.1 Introduction and History
    • • 10.2 Theoretical Background
    • • 10.3 Membrane Materials and Modules
    • • 10.3.1 Membrane Characterization
    • • 10.3.2 Membrane Materials
    • • 10.3.3 Membrane Modules
    • • 10.4 Process Design
    • • 10.4.1 Basic Principles
    • • 10.4.2 Hybrid Distillation/Membrane Processes
    • • 10.5 Applications
    • • 10.5.1 Bioethanol and Solvent Dehydration
    • • 10.5.2 VOC/Water Separations
    • • 10.5.3 Separation of Organic Mixtures
    • • 10.6 Conclusions and Future Directions
    • • References
  11. Chapter 11: Ion Exchange Membrane Processes

    • • 11.1 Introduction and History
    • • 11.2 Theoretical Background
    • • 11.2.1 Transport Through Ion Exchange Membranes
    • • 11.3 Chemistry of Ion Exchange Membranes
    • • 11.3.1 Homogeneous Membranes
    • • 11.3.2 Heterogeneous Membranes
    • • 11.4 Electrodialysis
    • • 11.4.1 Concentration Polarization and Limiting Current Density
    • • 11.4.2 Current Efficiency and Power Consumption
    • • 11.4.3 System Design
    • • 11.5 Electrodialysis Applications
    • • 11.5.1 Water Desalination
    • • 11.5.2 Continuous Electrodeionization and Ultrapure Water
    • • 11.5.3 Salt Recovery from Seawater
    • • 11.5.4 Other Electrodialysis Applications
    • • 11.6 Fuel Cells
    • • 11.7 Chlor-Alkali Processes
    • • 11.8 Other Electrochemical Processes
    • • 11.8.1 Water Splitting Using Bipolar Membranes
    • • 11.8.2 Redox Flow Batteries
    • • 11.8.3 Reverse Electrodialysis
    • • 11.9 Conclusions and Future Directions
    • • References
  12. Chapter 12: Carrier Facilitated Transport

    • • 12.1 Introduction
    • • 12.2 Facilitated Transport
    • • 12.2.1 Membrane and Process Development
    • • 12.2.2 Theory
    • • 12.2.3 Membranes
    • • 12.2.4 Applications
    • • 12.3 Coupled Transport
    • • 12.3.1 Membrane and Process Development
    • • 12.3.2 Theory
    • • 12.3.3 Coupled Transport Membrane Characteristics
    • • 12.3.4 Applications
    • • 12.4 Conclusions and Future Directions
    • • References
  13. Chapter 13: Membrane Contactors

    • • 13.1 Introduction
    • • 13.2 Contactor Modules
    • • 13.3 Applications of Membrane Contactors
    • • 13.3.1 Liquid/Liquid Contactor Applications
    • • 13.3.2 Liquid/Gas and Gas/Liquid Contactors
    • • 13.3.3 Gas/Gas Membrane Contactors
    • • 13.4 Conclusions and Future Directions
    • • References
  14. Chapter 14: Medical Applications of Membranes

    • • 14.1 Introduction
    • • 14.2 Hemodialysis
    • • 14.3 Plasma Fractionation
    • • 14.4 Blood Oxygenators
    • • 14.5 Controlled Drug Delivery
    • • 14.5.1 Membrane Diffusion-Controlled Systems
    • • 14.5.2 Monolithic Systems
    • • 14.5.3 Biodegradable Systems
    • • 14.5.4 Osmotic Systems
    • • References
  15. Chapter 15: Other Membrane Processes

    • • 15.1 Introduction
    • • 15.2 Metal Membranes
    • • 15.3 Ion-Conducting Membranes
    • • 15.4 Charge Mosaic Membranes and Piezodialysis
    • • References

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